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Porous Materials
Duncan W. Bruce (Editor)
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Últimas novedades
química inorgánica
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In the past few decades, the increasingly routine use of advanced structural probes for studying the structure and dynamics of the solid state has led to some dramatic developments in the field of porous solids. These materials are fundamental in a diverse range of applications, such as shape-selective catalysts for energy-efficient organic transformations, new media for pollutant removal, and gas storage materials for energy technologies. Porosity in inorganic materials may range from the nano-scale to the macro-scale, and the drive towards particular properties remains the goal in this fast-developing area of research. Covering some of the key families of inorganic solids that are currently being studied, Porous Materials discusses:
Metal Organic Frameworks Materials
Mesoporous Silicates
Ordered Porous Crystalline Transition Metal Oxides
Recent Developments in Templated Porous Carbon Materials
Synthetic Silicate Zeolites: Diverse Materials Accessible Through Geoinspiration
Additional volumes in the Inorganic Materials Series:
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Inorganic Materials Series Preface.
Preface.
List of Contributors.
1 Metal-Organic Framework Materials (Cameron J. Kepert).
1.1 Introduction.
1.2 Porosity.
1.2.1 Framework Structures and Properties.
1.2.2 Storage and Release.
1.2.3 Selective Guest Adsorption and Separation.
1.2.4 Heterogeneous Catalysis.
1.3 Incorporation of Other Properties.
1.3.1 Magnetic Ordering.
1.3.2 Electronic and Optical Properties.
1.3.3 Structural and Mechanical Properties.
1.4 Concluding Remarks.
Acknowledgements.
References.
2 Mesoporous Silicates (Karen J. Edler).
2.1 Introduction.
2.2 Nomenclature.
2.3 Methods of Preparation.
2.4 Surfactant Aggregation.
2.5 Silica Source.
2.6 Template Removal.
2.7 Synthetic Routes and Formation Mechanisms.
2.7.1 True Liquid Crystal Templating.
2.7.2 Cooperative Self-Assembly.
2.7.3 Evaporation-Induced Self-Assembly.
2.8 Properties and Characterisation.
2.9 Macroscopic Structures.
2.10 Applications.
References.
3 Ordered Porous Crystalline Transition Metal Oxides (Masahiro Sadakane and Wataru Ueda).
3.1 Introduction.
3.2 Scope and Limitations of this Review.
3.3 Microporous Transition Metal Oxide Materials.
3.4 Mesoporous Transition Metal Oxide Materials.
3.4.1 Soft Template Method.
3.4.2 Hard Template Method.
3.4.3 Mesoporous Oxides of Group 4 Elements (Ti, Zr).
3.4.4 Mesoporous Oxidesof Group 5 Elements (Nb, Ta).
3.4.5 Mesoporous Oxides of Group 6 Elements (Cr, Mo, W).
3.4.6 Mesoporous Oxides of Group 7 Elements (Mn).
3.4.7 Mesoporous Oxides of Elements of Groups 8–11 (Fe, Co, Ni, Cu).
3.4.8 Mesoporous Oxides of Lanthanide Elements (Ce).
3.5 Macroporous Materials.
3.5.1 Macroporous Monometal Oxides.
3.5.2 Macroporous Oxides of Group 4 Elements (Ti, Zr).
3.5.3 Macroporous Oxides of Group 5 Elements(V, Nb).
3.5.4 Macroporous Oxides of Group 6 Elements(Cr,W).
3.5.5 Macroporous Oxides of Elements of Groups 7–11 (Mn, Fe, Co, Ni, Cu).
3.5.6 Macroporous Oxides of Lanthanide Elements (La, Ce, Nd, Sm, Eu).
3.5.7 Macroporous Multi-Component Metal Oxides.
3.5.8 Two-Step Templating Method.
3.5.9 Applications.
3.6 Conclusion.
References.
4 Templated Porous Carbon Materials: Recent Developments (Yongde Xia, Zhuxian Yang and Robert Mokaya).
4.1 Introduction.
4.2 Microporous Carbon Materials.
4.2.1 Zeolites as Hard Template.
4.2.2 Clays as Hard Template.
4.2.3 Other Microporous Materials as Hard Template.
4.3 Mesoporous Carbon Materials.
4.3.1 Conventional Hard Template Synthesis Strategy.
4.3.2 Cost-Effective Strategies for the Synthesis of Mesoporous Carbons.
4.3.3 Soft-Template Synthesis Strategy for Ordered Mesoporous Carbons.
4.3.4 Ordered Mesoporous Carbons with Graphitic Pore Wall.
4.3.5 Mesopore Size Control.
4.3.6 Morphology Control.
4.4 Macroporous Carbon Materials.
4.4.1 Silica Colloidal Crystals as Hard Template.
4.4.2 Polymer Microspheres as Template.
4.4.3 Dual Template Method.
References.
5 Synthetic Silicate Zeolites: Diverse Materials Accessible Through Geoinspiration (Miguel A. Camblor and Suk Bong Hong).
5.1 Introduction.
5.2 Zeolites: Some Definitions.
5.3 Zeolite Structures.
5.4 Chemical Composition of Silicate Zeolites.
5.4.1 Naming Zeolites.
5.4.2 Loewenstein’s Rule.
5.5 Zeolite Properties.
5.6 Zeolite Applications.
5.7 Zeolite Synthesis.
5.7.1 The Synthetic Zeolites as Geoinspired Materials.
5.7.2 Thermochemistry of Zeolite Synthesis.
5.7.3 Organic Structure-Directing Agents.
5.7.4 Structure-Direction by Flexible, Hydrophilic OSDAs.
5.7.5 Double OSDA Strategies.
5.7.6 Structure-Direction by T-Atoms.
5.7.7 Zeolite Synthesis from Nonaqueous Solvents.
5.7.8 The Fluoride Route to Zeolites.
5.7.9 Structure-Direction Issues in the Fluoride Route to Pure-Silica Zeolites.
5.7.10 Topotactic Condensation of Layered Silicates.
5.8 Concluding Remarks.
Acknowledgements.
References.
Index.
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