ean 9780841227941 temática QUÍMICA GENERAL año Publicación 2014 idioma INGLÉS editorial OXFORD UNIVERSITY PRESS formato CARTONÉ 125,84 €    PEDIR

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química general

Discusses the latest techniques for integrating NMR spectroscopy in undergraduate courses. Developed from presentations given at the 239th ACS National Meeting in San Francisco. Even the most cursory survey of the chemical literature reveals that modern NMR spectroscopy has indeed fulfilled its potential as a powerful and indispensable tool for probing molecular structure, providing detail that is comparable to, and sometimes surpasses that, of X-ray crystallography. As NMR spectroscopy’s 70th anniversary approaches, the diversity of chemical problems to which this technique can be applied continues to grow across many scientific fields. Beyond the laboratory setting, the technology underlying NMR is now a widely used and critical medical diagnostic technique, Magnetic Resonance Imaging (MRI). Unfortunately, the number of applications of NMR spectroscopy across so many STEM-related fields presents significant challenges in how best to introduce this powerful technique in meaningful ways at the undergraduate level. Inspired by the development of the field, and building upon the work of previous symposia and an ACS symposium series book on this topic (3), a symposium was developed, entitled "NMR Spectroscopy in the Undergraduate Curriculum," for the 239th American Chemical Society National Meeting in San Francisco. This book brings together all of the presenters who have been successful in developing and successfully integrating NMR spectroscopy pedagogy across their undergraduate curriculums. Their knowledge and experiences will aid readers who are interested in expanding and invigorating their own curriculum.

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preface 1. Introduction to NMR Spectroscopy in the Undergraduate Curriculum Anton S. Wallner, Laura J. Anna, and David Soulsby 2. Modern NMR Experiments: Applications in the Undergraduate Curriculum David Soulsby Organic Chemistry 3. Data versus Dogma: Introducing NMR Early in Organic Chemistry To Reinforce Key Concepts Paul A. Bonvallet and Judith C. Amburgey-Peters 4. Using NMR Spectroscopy To Promote Active Learning in Undergraduate Organic Laboratory Courses John A. Cramer 5. NMR Spectroscopy in Nondeuterated Solvents (No-D NMR): Applications in the Undergraduate Organic Laboratory John E. Hanson 6. Overcoming Problems Incorporating NMR into the Organic Chemistry Lab Luke A. Kassekert and J. Thomas Ippoliti 7. Using NMR To Investigate Products of Aldol Reactions: Identifying Aldol Addition versus Condensation Products or Conjugate Addition Products from Crossed Aldol Reactions of Aromatic Aldehydes and Ketones Nanette M. Wachter 8. Use of HSQC, HMBC, and COSY in Sophomore Organic Chemistry Lab V. R Miller Inorganic/Heteronuclear Chemistry 9. 31P NMR Spectroscopy in an Undergraduate Inorganic Curriculum Chip Nataro, Chelsea L. Mandell, and Margaret A. Tiedemann 10. Using 195Pt and 31P NMR To Characterize Organometallic Complexes: Heteronuclear Coupling in the Presence of Geometric Isomers Daron E. Janzen, Mainong Hang, and Hannah M. Kaup 11. Beyond Ordinary Undergraduate Experiences: Routine Measurements with Heteronuclear, Heterogeneous, and Paramagnetic Samples Patrick J. Desrochers Physical Chemistry and Biochemistry 12. Substituent Interactions in Aromatic Rings: Student Exercises Using FT-NMR and Electronic Structure Calculations James B. Foresman and Donald D. Clarke 13. Using NMR Spectroscopy To Elucidate the Effect of Substituents on Keto-Enol Equilibria Anderson L. Marsh 14. NMR-Based Kinetic Experiments for Undergraduate Chemistry Laboratories Eric J. Kantorowski, Bijan D. Ghaffari, Allee Macrorie, Kellan N. Candee, Jennifer M. Petraitis, Melanie M. Miller, Gayle Warneke, Michelle Takacs, Vanessa Hancock, and Zoe A. Lusth 15. Physical Chemistry Laboratory Projects Using NMR and DFT-B3LYP Calculations A. C. Bagley, C. C. White, M. D. Mihay, and T. C. DeVore 16. 1H NMR MAS Investigations of Phase Behavior in Lipid Membranes Holly C. Gaede NMR Spectroscopy Across the Undergraduate Curriculum 17. Vertical Integration of NMR in the Chemistry Curriculum: A Collaborative Advanced Laboratory Experiment Examining the Structure-Reactivity Relationships in Carbonyl Reduction Sheila R. Smith and Simona Marincean 18. NMR Spectroscopy in the Undergraduate Curriculum at the University of Notre Dame Steven M. Wietstock, Kathleen A. Peterson, DeeAnne M. Goodenough Lashua, Douglas A. Miller, and James F. Johnson NMR Spectroscopy: Collaborative Strategies, Resources, and Grant Writing 19. Oregon NMR Consortium: A Collaboratory for NMR Data Acquisition and Processing R. Carlisle Chambers 20. ChemSpider: How a Free Community Resource of Data Can Support the Teaching of NMR Spectroscopy Antony J. Williams, Valery Tkachenko, and Alexey Pshenichnov 21. Writing More Competitive Grant Proposals for NMR Spectrometers: Research and Curriculum Programs of the National Science Foundation Thomas J. Wenzel Editors’ Biographies Indexes Author Index Subject Index