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Handbook of Transition Metal Polymerization Catalysts
Ray Hoff (Editor), Robert T. Mathers (Ed
Handbook of Transition Metal Polymerization Catalysts
ean9780470137987
temáticaQUÍMICA GENERAL
año Publicación2010
idiomaINGLÉS
editorialWILEY
páginas575
formatoCARTONÉ


121,00 €


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química general
A one-stop resource for understanding and applying polymerization catalysts

An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these important catalysts.

With both recent advances and historically important catalysts, the subjects covered in this text include:

Metal alkyls and other compounds that function as co-catalysts with a large number of catalysts

The varieties of porous silica either necessary or valuable in certain catalyst formulations

Catalyst scale-up and commercialization

Copper catalysts for olefin polymerization

Morphology control

Along with the above topics, the Handbook of Transition Metal Polymerization Catalysts provides tables of valuable data to assist in reproducing a synthesis or applying the knowledge to a new problem. Polymerization reactivities, polymer properties, monomer and solvent purity requirements, molecular weights, distribution, and reactivity ratios are also covered. The Handbook of Transition Metal Polymerization Catalysts offers an excellent one-stop resource for understanding and applying polymerization catalysts.

indíce
Introduction (Ray Hoff).
Authors.

Chapter 1: Commercially Available Metal Alkyls and Their Use in Olefin Polymerization (Dennis B. Malpass).

Chapter 2: Porous Silica in Transition Metal Polymerization Catalysts (Thomas J. Pullukat and Robert E. Patterson).

Chapter 3: Computational Modeling of Transition Metal polymerization Catalysts (Monika Srebro and Artur Michalak).

Chapter 4: Scale Up of Catalyst Recipes to Commercial Production (C.P. Cheng).

Chapter 5: Commercialization of Olefin Polymerization Catalysts (C. E. Capshew).

Chapter 6: Supported Titanium-Containing Ziegler Catalysts for the Production of Polyethylene (Thomas E. Nowlin, Robert L. Mink, and Yury V. Kissin).

Chapter 7: Stereospecific Polymerization with “Traditional“ Ziegler-Natta Catalysts (John Severn and Robert L. Jones).

Chapter 8: MgCl2-Supported TiCl4 Catalysts for the Production of Morphology Controlled Polyolefins (Long Wu and Sieghard E Wanke).

Chapter 9: Product Morphology in Olefin Polymerization with Polymer Supported Metallocene Catalysts (Long Wu and Sieghard E. Wanke).

Chapter 10: Phillips Chromium Catalysts for Ethylene Polymerization (Max McDaniel).

Chapter 11: Silica Supported Silyl Chromate Based Ethylene Polymerization Catalysts (Kevin Cann).

Chapter 12: Ethylene Polymerization and a-Olefin Oligomerization Using Catalysts Derived from Phosphoranes and Ni(II) and Ni(0) Precursors (Scott Collins).

Chapter 13: Late Transition Metal Catalyzed Co- And Terpolymerization of a-Olefins with Carbon Monoxide – Polyketones; Synthesis and Modification (Timo M. J. Anselment, Manuela Zintl, Maria Leute, Ruediger Nowack and Bernhard Rieger).

Chapter 14: Copper Catalysts for Olefin Polymerization (Anna Maria Raspolli Galletti).

Chapter 15: Ring Opening Metathesis Polymerizations (ROMP) and Acyclic Diene Metathesis (ADMET) Polymerizations with Homogeneous Ruthenium and Molybdenum Catalysts and Initiators (Robert T. Mathers).

Chapter 16: Cobalt Ziegler-Natta Catalysts for the Synthesis of cis-Poly-1,4-butadiene (Ray Hoff).

Appendix 1: Pyrophoricty of Metal Alkyls (Dennis B. Malpass).

Appendix 2: Rheological Terms for Polymerization Catalyst Chemists (Gregory W. Kamykowski, TA Instruments).

INDEX.

Finançat per UE