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Advances in Silicones and Silicone-Modified Materials
Stephen Clarson, Michael Owen
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Últimas novedades química general
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Silicon, silica and silicones each have important but separate technological roles to play for mankind in this millennium. All three have the element silicon (Si) in common but they have unique and distinctive chemistries, properties and applications. This book describes recent advances in silicones and the advanced materials which are based on the siloxane bond (Si-O).
We have seen tremendous developments in silicon-based materials over the past century and yet clearly there is still much potential for new advanced materials based on the siloaxne bond. With the high abundance of silicon and oxygen on Earth, we are probably working with the most sustainable and "green" materials if we adopt the correct materials chemistry, materials processing, materials recovery and materials reuse strategies.
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Preface Dedication
Introduction 1. Advanced Materials Containing the Siloxane Bond Stephen J. Clarson
Silicones 2. Properties and Applications of Silicones Michael J. Owen 3. Polymorphs of Octaphenylcyclotetrasiloxane Abhilasha M. Baruah, Anirban Karmakar, and Jubaraj B. Baruah 4. Synthesis and Characterization of Cycloaliphatic Siloxanes Copolymers Ruby Chakraborty and Mark D. Soucek 5. Trypsin-Catalyzed Cross-Linking of ?,?-Triethoxysilyl-Terminated Polydimethylsiloxane: An Experimental and Computational Approach Paul M. Zelisko, Travis Dudding, Karen R. Arnelien, and Heidi Stanisic 6. Viscoelastic Behavior of Polydimethylsiloxane Stabilized Magnetite Magnetic Nanoparticle Complexes Wen Yin, Qiongdan Xie, Jianjun Deng, Jonathan D. Goff, Timothy P. Vadala, Judy S. Riffle, and Alan R. Esker 7. Characterization of Complex Engineering Silicones by 1H Multiple Quantum NMR and Large Scale Molecular Dynamics Simulations Robert S. Maxwell, Richard H. Gee, Theodore Baumann, Naida Lacevic, Julie L. Herberg, and Sarah C. Chinn 8. Characterization of a Biomedical Grade Silica-Filled Silicone Elastomer Using Ultrasound Alexander R. Anim-Mensah, Jeffrey E. Franklin, Aniruddha S. Palsule, Luis A. Salazar, Christopher W. Widenhouse, David B. Mast, James E. Mark, William B. Krantz, and Stephen J. Clarson 9. Fluorosilicones Michael J. Owen
Copolymers, Networks and Dendrimers 10. Fluorine-Containing Organosilicon Polymers of Different Architectures Synthesis and Properties Study N. A. Sheremetyeva, N. V. Voronina, A. V. Bystrova, V. D. Miakushev, M. I. Buzin, and A. M. Muzafarov 11. Radially Layered Poly(amidoamine-organosilicon) Dendrimers Petar R. Dvornic and Michael J. Owen 12. Etching of Silicone Elastomers: Controlled Manipulation of Surface Roughness Michael A. Brook, Lihua Liu, Shigui Zhao, and Zaid N. Mammo 13. Novel Organo-Siloxane Copolymers for Flame Retardant Applications Ravi Mosurkal, Vincent Tucci, Lynne A. Samuelson, Kenneth D. Smith, Phillip R. Westmoreland, Virinder S. Parmar, Jayant Kumar, and Arthur C. Watterson 14. An Investigation into the Influence of Crosslinker Type and Solvent Composition on Physical Properties and Phase Transition Behavior of Poly(N-isopropylacrylamide) Hydrogels Candan Erbil, Ezgi Toz, Özgür Akdemir, and Nurseli Uyan?k
Polyhedral Oligomeric Silsesquioxanes 15. Ion Effects on Trisilanolphenyl-POSS as an Adhesion Promoter Sarah M. Huffer, Ufuk Karabiyik, Joshua R. Uzarski, and Alan R. Esker 16. Polyhedral Oligomeric Silsesquioxane-Functionalized Perfluorocyclobutyl Aryl Ether Polymers Scott T. Iacono, Stephen M. Budy, Joseph M. Mabry, and Dennis W. Smith, Jr. 17. What Does It Take To Make a Stable POSS®/Polymer Composite? David A. Schiraldi and Subramanian Iyer
Silica 18. The Role of Non-Bonded Interactions in Silica Formation in Vitro Siddharth V. Patwardhan, David Belton, Graham Tilburey, and Carole C. Perry Applications of Silicones and Silicone-Modified Materials 19. Function of Silicon-Oxygen Bonds in Fabrication of Holographic Gratings Yusuke Kawakami and Yeong Hee Cho 20. Foam Control Michael J. Owen
Indexes Author Index Subject Index
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