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Chemical Technology: An Integral Textbook
Andreas Jess, Peter Wasserscheid
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Últimas novedades biotecnología
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The first major textbook to provide an integral and integrated treatment of industrial-relevant problems for students of both chemistry and chemical engineering. As such, this work combines the four disciplines of chemical technology -- chemistry, thermal and mechanical unit operations, chemical reaction engineering and general chemical technology -- and is organized into two main parts. The first covers the fundamentals, as well as the analysis and design of industrial processes, while the second section presents 30 concrete processes, exemplifying the inherent applied nature of chemical technology. These are selected so that they all differ with respect to at least one important aspect, such as the type and design of the reactor, the chemistry involved or the separation process used. As a result, readers will recapitulate, deepen and exercise the chemical and engineering principles and their interplay, as well as being able to apply them to industrial practice. Instructive figures, rules of thumb for swift but reliable estimating of parameters, data of chemical media, and examples utilizing data from industrial processes facilitate and enhance the study process. A small general survey of selected modern trends, such as multifunctional and micro reactors, or new solvents for homogeneous catalysis, such as ionic liquids, point out to the reader that this is not a concluded discipline, but a developing field with many challenges waiting to be solved. |
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INTRODUCTION What is Chemical Technology? The Chemical Industry CHEMICAL ASPECTS OF INDUSTRIAL CHEMISTRY Stability and Reactivity of Chemical Bonds General Classification of Reactions Catalysis THERMAL AND MECHANICAL UNIT OPERATIONS Properties of Gases, Liquids and Solids Transport Processes Thermal Unit Operations Mechanical Unit Operations CHEMICAL REACTION ENGINEERING Main Aspects and Basic Definitions of Chemical Reaction Engineering Chemical Thermodynamics Kinetics of Homogeneous Reactions Kinetics of Fluid-Fluid-Reactions Kinetics of Heterogeneously Catalysed Reactions Kinetics of Gas-Solid Reactions Criteria for Exclusion of Mass and Heat Transfer Limitations in Gas-Solid and Heterogeneously Catalysed (Single Phase) Reactions Kinetics of Homogeneously Catalysed Reactions Kinetics of Gas-Liquid Reactions on Solid Catalysts Chemical Reactors Measurement and Evaluating of Kinetic Data RAW MATERIALS, PRODUCTS AND ENVIRONMENTAL AND COST ASPECTS OF CHEMICAL TECHNOLOGY Raw Materials and Energy Sources Inorganic Products Organic Intermediates and Final Products Environmental Aspects of Chemical Technology Manufacturing of Fuels and Chemicals: Energy Consumption and Costs EXAMPLES OF INDUSTRIAL PROCESSES Ammonia Synthesis Syngas and Hydrogen Sulphuric Acid Nitric Acid Coke and Steel Basic Chemicals by Steam Cracking Liquid Fuels by Cracking of Heavy Oil Clean Fuels by Hydrotreating High Octane Gasoline by Reforming Refinery Alkylation Fuels and Chemicals from Syngas: Methanol and Fischer-Tropsch-Synthesis Ethylene and Propylene-Oxide Catalytic Oxidation of o-Xylene to Phthalic Acid Anhydride Hydroformylation (Oxosynthesis) Acetic Acid Ethylene Oligomerization Processes for Linear 1-Alkene Production Production of Fine Chemicals in a Batch Reactor: Example Menthol Treatment of Exhaust Gases from Mobile and Stationary Sources Industrial Electrolysis Polyethylene
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